Clathrochelates: Synthesis, Structure and Properties (ReUp)

Description

Clathrochelates are compounds which contain a metal ion encapsulated within a three dimensional cage of macrobicyclic ligand atoms. Within this cage the metal has unique properties and is to a great extent isolated from environmental factors. Such complexes are suitable as models of the most essential biological systems, membrane transport, electron carriers, highly selective and sensitive analytical reagents, catalysts for photochemical and redox processes, cation and anion receptors, etc. The aim of this monograph is to generalize and analyze experimental and theoretical data on clathrochelates in order to promote further research in this promising field of chemistry.

Chapter 1 gives general concepts of complexes with encapsulated metal ions, discusses basic specific features of these compounds, considers and characterizes the main types of compounds with encapsulated metal ions and the main classes of clathrochelates, and includes the current nomenclature. Chapter 2 deals with the pathways of clathrochelate synthesis and the general procedures for the synthesis of macrobicyclic tris-dioximates, phosphorus-containing tris-diiminates, sepulchrates, sarcophagi-nates, and polyene and other types of clathrochelate complexes. Chapter 3 concerns studies of the electronic and spatial structure of clathrochelate complexes. In Chapter 4, the kinetics and mechanism of synthesis and decomposition reactions of macrobicyclic tris-dioximates, sarcophaginates, and sepulchrates in solution and gas phases are discussed. Chapter 5 considers the electrochemical, photochemical, and some other characteristics of clathrochelates and their applications associated with these characteristics. Finally, the practical applications of the unique properties of clathrochelates and perspectives on the synthesis of new clathrochelates are described in Chapters 6 and 7, respectively.

Disclaimer:
Contents of this page are indexed from the Internet. All actions are under your responsability. Email us to report illegal contents or external links and we'll remove them immediately.

Please check the description for download links if any or do a search to find alternative books.

Can't Download?
Please search mirrors if you can't find download links for "Clathrochelates: Synthesis, Structure and Properties (ReUp)" in "Description" and someone else may update the links. Check the comments when back to find any updates.

Search Mirrors
Maybe some mirror pages will be helpful, search this book at top of this page or click here to find more info.

1. Ebooks list page : 3290
2. From the Molecular to the Nanoscale: Synthesis, Structure, and Properties
3. Carbon Nanotubes: Synthesis, Structure, Properties and Applications
4. Metal Complexes and Metals in Macromolecules: Synthesis, Structure and Properties
5. Ceramic and Glass Materials: Structure, Properties and Processing (ReUp)
6. Precursor-Derived Ceramics: Synthesis, Structure and High-Temperature Mechanical Properties
7. Non-Covalent Multi-Porphyrin Assemblies: Synthesis and Properties (Structure and Bonding) by Enzo Alessio (Editor)
8. Carbon Nanotubes: Advanced Topics in the Synthesis, Structure, Properties and Applications (Topics in Applied Physics)
9. Polyynes: Synthesis, Properties, and
10. The Structure and Properties of Water
11. Polyynes: Synthesis, Properties, and Applications
12. Foldamers: Structure, Properties, and Applications
13. Foldamers: Structure, Properties, and Applications
14. Structure And Properties of Atomic Nanoclusters
15. Ultrananocrystalline Diamond: Synthesis, Properties, and Applications
16. Ultrananocrystalline Diamond: Synthesis, Properties, and Applications