Comprehensive Chemical Kinetics, Volume 18: Selected Elementary Reactions

Description

This section, which consists only of Volume 18, deals with certain types of elementary reactions, occurring in the gas and liquid phases, which either have not been covered at all in the previous sections or have appeared fragmentarily or scattered among various volumes and chapters. Much of the information is summarized in tabular or graphical form and, as far as possible, the data have been assessed critically and correlated. Chapter 1 deals with the kinetics of the dissociation of diatomic molecules and the recombination of atoms, and Chapters 2 and 3 with the
reactions of atoms and radicals with molecules, abstraction (metathetical) processes and addition to double and triple bonds. Data for the reactions of metal atoms with a variety of inorganic, organic and metal organic compounds, derived from “sodium flame” and molecular beam techniques, are discussed in Chapter 4 and rapid substitution at labile metal ions in solution in Chapter 5. The theory of, and the experimental results for, ion-molecule reactions, i.e. chemical processes resulting from binary collisions of positive or negative ions with neutral molecules, are discussed in Chapter 6 and the reactions of solvated electrons in Chapter 7.

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