From the Molecular to the Nanoscale: Synthesis, Structure, and Properties

Description

In this volume recent progress in synthetic coordination chemistry, which has led to the production of materials displaying nanoscopic structural motifs, is described. The availability of increasingly powerful structure determination methods such as area detection for single-crystal X-ray diffraction and high-energy electron microscopies has been a key aspect to the development of this area. It is now possible to determine the structures of very large clusters, aggregates of metal ions, and coordination polymers to atomic resolution on a routine basis. For example, the field of coordination polymers has been explosively developed thanks to the advances in X-ray diffraction methods. The results of such structure determinations are fed back to the precise design of the structures and properties of coordination materials. For example, unique properties of coordination polymers (gas absorption, magnetism, etc.) have been explored through molecular-level designing.

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