New Aspects in Phosphorus Chemistry V: Topics in current chemistry, 250 by: Volume Editor: Jean-Pierre Majoral

Description

Polyphosphazenes have been known for a long time.However their synthesis and properties continue to attract interest because of the broad range of applications of these polymers in different fields ranging from biology to new materials. The contribution of M. Gleria and R. de Jaeger reports the variety of synthetic procedures based on the ring-opening polymerization of monomers such as (NPCl2)3 and (NPCl2)n followed by the nucleophilic replacement of the reactive chlorines with selected nucleophiles and on polycondensation reaction processes of new monomers and of phosphoranimines. The use of polyphosphazenes as fluoroelastomers, flame retardants and self-extinguishing macromolecules, polymeric ionic conductors,biomaterials, and photosensitive polymeric compounds is outlined. This volume,as well as the four precedent volumes,describes only in part the huge number of original papers on phosphorus-related topics. Some further volumes will be necessary in the future to cover all aspects of this chemistry in perpetual rebirth.

Table of contents
S. Constant, J. Lacour: Hexacoordinated Phosphorus Chemistry .-
S. Marque, P. Tordo: Reactivity of Phosphorus Centred Radicals .-
M. Alajarin, C. López-Leonardo, P. Llamas-Lorente: The Chemistry of Phosphinous Amides (Aminophosphanes): Old Reagents with New Applications .-
D.P. Gates: Expanding the Analogy Between P=C and C=C Bonds to Polymer Science .-
M. Hissler, P.W. Dyer, R. Reau: The Rise of Organophosphorus Derivatives in p-Conjugated Material Chemistry .-
M. Gleria, R. de Jaeger: Polyphosphazenes

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