Silicon-mediated Transformations of Functional Groups

Description

In the first work to comprehensively cover this all-important topic, the recognized expert Helmut Vorbr?provides both organic and bioorganic chemists with much new and valuable information for preparative synthesis.

Although every organic chemist may be familiar with different aspects of silylation for the protection of functional groups, this book covers the concept of protection while simultaneously silylating-activating various functional groups, such as amides and ureas. This novel methodology opens thus numerous synthetic pathways while effecting the elimination of water in it volatile persilylated form under rather mild reaction conditions, which are often advantageous compared to conventional methods.

The compact form and clear structure of this monograph make this a long-awaited ready reference.

From the contents:

* Introduction
* Techniques of Preparative Silylations-Desilylations
* Preparation and Properties of Siliconoxy-Leaving Groups
* Reactions of Free and Derivatized Carboxylic Acids and Carbon Dioxide
* Reactions of Aldehydes and Ketones
* Reactions of Alcohols, Ethers and Epoxides
* Reaction of N-O Systems
* Reactions of S-O and Se-O Systems
* Cyclizations and Ring Enlargements
* Base and Acid-Catalyzed as well as Thermal Eliminations of Trimethylsilanol. Peterson Reactions
* Formation of Carbon-Phosphorous Double- and Triple Bonds
* Reductions and Oxidations
* Dehydration-Activation as well as Silylation of Inorganic and Organic Salts and Metalorganic Compounds
* Formation of Polymers


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1. Ebooks list page : 2788
2. Shape and Functional Elements of the Bulk Silicon Microtechnique: A Manual of Wet-Etched Silicon Structures
3. Continuous Groups of Transformations (Dover Phoenix Editions): : Luther Pfahler Eisenhart
4. By Boyd, "Personal Transformations in Small Groups: A Jungian Perspective"
5. Name Reactions of Functional Group Transformations (Comprehensive Name Reactions) by: Jie Jack Li, E. J. Corey
6. Supplement C2: The Chemistry of Triple-Bonded Functional Groups, Vol. 2
7. Supplement A3: The Chemistry of Double-Bonded Functional Groups
8. Functional Analysis and Semi-groups (Colloquium Publications (Amer Mathematical Soc))
9. The Chemistry of Cyclobutanes (Chemistry of Functional Groups) by: Zvi Rappoport and Joel F. Liebman (Editors)
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12. The Chemistry of Organic Germanium, Tin and Lead Compounds (Chemistry of Functional Groups)
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